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5)-cyclopentadienyl](l-a-oxidobenzylidene-1:2j 2 O:C)titanium(IV)tungsten(0)

By Catharine Esterhuysen, I. B. Jacques Nel, Matthias W and Stephanie Cronje

Abstract

R factor = 0.025; wR factor = 0.062; data-to-parameter ratio = 15.2. The title compound, [TiW(C 5H 5) 2(C 7H 5O)Cl(CO) 5], consists of two metal centres, with a (tungstenpentacarbonyl)oxyphenylcarbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2) with respect to this plane. One of the cyclopentadienyl rings undergoes an offset face-to-face – interaction [3.544 (6) A ˚ ] with the symmetry-related cyclopentadienyl ring of a neighbouring molecule. Related literature For related literature regarding anionic Fischer-type carbenes, see: Barluenga & Fañanás (2000). For information regarding the catalytic activity of similar complexes, see: Luruli et al. (2004, 2006); Sinn et al. (1980). For comparable structures, see: Esterhuysen et al. (2008); Balzer et al. (1992). For related literature, see: Orpen et al. (1989)

Topics: wR(F 2) = 0.062
Year: 2008
OAI identifier: oai:CiteSeerX.psu:10.1.1.351.9911
Provided by: CiteSeerX
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