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By R. Sivaramakrishnan, M. -c. Su, J. V. Michael, L. B. Harding, B. Ruscic and F C H Oh

Abstract

The thermal decomposition of ethanol and its reactions with OH and D have been studied with both shock tube experiments and ab initio transition state theory-based master equation calculations. Dissociation rate constants for ethanol have been measured at high T in reflected shock waves using OH optical absorption and high-sensitivity H-atom ARAS detection. The three dissociation processes that are dominant at high T ar

Year: 2010
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