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2. Nitrene or Carbene Insertion into a C-H Bond

By Jinhua J. Song, Jonathan T. Reeves, Daniel R. F, Zhulin Tan, Nathan K. Yee, Chris H. Senanayake and Transition-metal Catalyzed C-h Amination


This review article summarizes C-H functionalization-based synthesis of indoles and related structures (e.g. carbazoles and indolines) with an emphasis on literature after 2000. The discussion is organized into four broadly defined sections: a) via nitrene or carbene insertion into a C-H bond; b) via direct coupling of two sp 2 carbon centers; c) via transition-metal catalyzed C-H amination and d) other strategies. Keywords: C-H functionalization, indole, carbazole, indolin

Year: 2011
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