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Advances in the chemistry of stable nitroxides

By Leonid B. Volodarsky and I L. B. Volodarsky


Abstract- The paper discusses syntheses of new nitroxides by structure modifications of known carbocyclic and heterocyclic nitroxides and their diamagnetic precursors, as well a6 syntheses of nitroxides with a functional group in close proximity to the radical centre. It demonstrates a new route to pyrrolidine nitroxides. Much has been focused on 3-imidazoline and 3-imidazoline-3-oxide nitroxides owing to their stability to acids and oxidants, complexing ability and remarkable reactivity. The progress in the chemistry of nitroxides is largely stimulated by expanding scientific and practical applications of these compounds, On the other hand, creation of new structural types gives rise to new applications of nitroxides. This paper presents compounds and methods of their synthesis realized during recent years and unsynthesized compounds whose synthesis may be outlined based on our current knowledge, Such cornpounds are under

Year: 2009
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