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Cis-Trans Isomerism among the Octahedral Anionobis(C-substituted ethylenediamine)nickel(II) Complexes Obtained by Thermal Reactions

By Yoshinori Ihara, Yutaka Fukuda and Kozo Sone

Abstract

Ten octahedral anionobis(C-substituted ethylenediamine)nickel(II) complexes were obtained by thermal reactions of corresponding diaqua salts, and their electronic and IR spectra were examined to see whether they are cis or trans. Most of them were found to be trans, but [Ni(NO3)(m-bn)2](NO3) and [NiCl2(i-bn)2] were cis

Publisher: 日本化学会=The Chemical Society of Japan
Year: 1986
DOI identifier: 10.1246/bcsj.59.1825
OAI identifier: oai:dspace.lib.kanazawa-u.ac.jp:2297/37510
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