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Photochemistry with fast sample renewal using cluster beams: formation of rare-gas halides in charge-transfer reactions in NF3-doped rare-gas clusters

By L. Moussavizadeh, Klaus von Haeften, L. Museur, A. V. Kanaev, M. C. Castex, R. von Pietrowski and Thomas Möller


Metadata only entryCharge transfer reactions in free clusters are observed in a photoluminescence study on doped rare-gas clusters (Rg clusters, Rg=Ar, Kr and Xe). Following photoexcitation into the first absorption bands of Rg clusters, fluorescence from free RgF* excimers ejected from the clusters and from Rg2F* excimers localized in the interior of the clusters is observed. The results show that the reaction dynamics in clusters differs considerably from that in the gas and solid phase

Publisher: Elsevier
Year: 1999
DOI identifier: 10.1016/S0009-2614(99)00390-5
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