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A metal-mediated diastereoselective synthesis of precursors to the aphid pigment derivatives

By R.G.F. Giles, C.A. Joll, M.V. Sargent and D.G. Tilbrook

Abstract

Chiral compounds 16 and 17, precursors to the aphid insect pigment derivatives, have been prepared in good to high yield, with complete control of the diastereoselectivity at the newly-created chiral centre C-1, through the use of metal phenolates derived from naphthol 3

Publisher: Elsevier BV
Year: 1996
OAI identifier: oai:researchrepository.murdoch.edu.au:19137
Provided by: Research Repository
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