Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes

Ruamps, Mirko; Bastin, S.; Rechignat, Lionel; Sournia-Saquet, Alix; Valyaev, Dmitry A.; Mouesca, J.-M.; Lugan, Noël; Maurel, V.; César, Vincent

oai:HAL:hal-01948412v1

Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes

Authors: Mirko Ruamps
S. Bastin
Lionel Rechignat
Alix Sournia-Saquet
Dmitry A. Valyaev
J.-M. Mouesca
Noël Lugan
V. Maurel
Vincent César
Publication date: January 1, 2018
Publisher: 'Royal Society of Chemistry (RSC)'
Doi

Abstract

International audienceIMes-derived thioureas in which the imidazolyl ring is directly substituted by one or two dimethylamino groups are redox-active, exhibiting one and two oxidized states, respectively. The structure, stability, and electronics of the oxidized species are investigated, emphasizing the decisive role of the amino substituents

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oai:HAL:hal-01948412v1Last time updated on 1/17/2019

This paper was published in HAL-CEA.

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