Article thumbnail
Location of Repository

Head-To-Tail and Heteroleptic Pentanuclear Circular Helicates

By Kirsty E. Allen, Robert A. Faulkner, Lindsay P. Harding, Craig R. Rice, Thomas Riis-Johannessen, Melanie L. Voss and Martina Whitehead

Abstract

Everybody form a circle: Careful design of ligand strands and their reaction with Cu2+ ions leads to the formation of the title helicates. Incorporation of differing numbers of N-donor units within a ligand strand containing a phenyl spacer results in a pentanuclear head-to-tail circular helicate, whereas reaction of two different ligands results in a heteroleptic pentanuclear circular helicate (see picture; green: Cu, red and blue: ligands)

Topics: QD
Publisher: Wiley
Year: 2010
OAI identifier: oai:eprints.hud.ac.uk:8234
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • http://dx.doi.org/10.1002/anie... (external link)
  • http://www2.hud.ac.uk/staffpro... (external link)
  • Suggested articles


    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.