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Controlling the formation of metallosupramolecular assemblies by metal ionic radii

By Lindsay Bain, Sam Bullock, Lindsay P. Harding, Thomas Riis-Johannessen, Gary Midgley, Craig R. Rice and Martina Whitehead


The formation of either dinuclear double-stranded or pentanuclear circular helicates from a ligand containing two tridentate domains separated by a phenylene unit can be controlled by inter-ligand steric interactions which themselves are governed by the size of the metal io

Topics: Q1, QD
Publisher: Royal Society of Chemistry
Year: 2010
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