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Equilibria between enamine and B-unsaturated imine in cephalosporin hydrolysis

By Stephen C. Buckwell, Michael I. Page and Jethro L. Longridge


The normal product of hydrolysis of cephalosporins with a leaving group at C-3 is an ,-unsaturated imine which is demonstrated to be in equilibrium with its precursor, an enamine; the equilibrium constants for this process are reported for thiolate anions which generate a Bronsted lg of 0.7

Topics: Q1, QD
Publisher: Royal Society of Chemistry
Year: 1986
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