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Anion control of ligand self-recognition in a triple helical array

By Lindsay P. Harding, John C. Jeffery, Thomas Riis-Johannessen, Craig R. Rice and Zuotao Zeng


Self-assembly of the ligand L1 with Co2+ into a dinuclear triple helicate [Co2(L1)3]4+ produces an anion binding pocket which encapsulates perchlorate anions. Furthermore we demonstrate how this ability to bind anions can control ligand self-recognition properties

Topics: Q1, QD
Publisher: Royal Society of Chemistry
Year: 2004
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