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Investigations on the preparation, oxidation and reduction reactions of thiophosphoryl fluoride

By DK Padma, SK Vijayalakshmi and AR Vasudevamurthy


Pure thiophosphoryl fluoride has been prepared by the fluorination of thiophosphoryl chloride by sodium fluoride in acetonitrile medium. Oxidation of this phosphoryl fluoride by acidified chloramine-T ruptures the phosphorus-sulphur bond and oxidises the sulphur present to the hexavalent state. Anhydrous hydrogen iodide reduces the sulphur to hydrogen sulphide and phosphorus to the trivalent state

Topics: Inorganic & Physical Chemistry
Publisher: Elsevier Science
Year: 1976
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