Investigations on the preparation, oxidation and reduction reactions of thiophosphoryl fluoride

Abstract

Pure thiophosphoryl fluoride has been prepared by the fluorination of thiophosphoryl chloride by sodium fluoride in acetonitrile medium. Oxidation of this phosphoryl fluoride by acidified chloramine-T ruptures the phosphorus-sulphur bond and oxidises the sulphur present to the hexavalent state. Anhydrous hydrogen iodide reduces the sulphur to hydrogen sulphide and phosphorus to the trivalent state

Download PDF:
_{Sorry, we are unable to provide the full text but you may find it at the following location(s):}

http://eprints.iisc.ac.in/2396... (external link)

http://eprints.iisc.ac.in/2396... (external link)