Article thumbnail

On the stability of lithium during ageing of $Li/PEO_8LiClO_4/Li cells$

By N Munichandraiah, AK Shukla, LG Scanlon and RA Marsh

Abstract

Symmetrical cells consisting of a thin film of $PEO_8LiClO_4$ solid-polymer electrolyte sandwiched between two lithium electrodes have been subjected to galvanostatic polarization and concomitant voltage changes measured at several intervals of ageing at ambient temperature. The interfacial resistance is found to increase gradually over about 150 days of ageing. The exponential increase of cell voltage is interpreted in the light of the diffusion-limited lithium-ion transport across the passive surface film on lithium

Topics: Solid State & Structural Chemistry Unit, Inorganic & Physical Chemistry
Publisher: Elsevier
Year: 1996
OAI identifier: oai:eprints.iisc.ac.in:9327
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • http://eprints.iisc.ac.in/9327... (external link)
  • http://eprints.iisc.ac.in/9327... (external link)
  • Suggested articles


    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.