10.1007/b11151

Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems

Abstract

Schoeller W. Donor-acceptor complexes of low-coordinated cationic pi-bonded phosphorus systems. NEW ASPECTS IN PHOSPHORUS CHEMISTRY III. 2003;229:75-94.Cationic low-coordinated pi-bonded phosphorus compounds add Lewis donors, such as amines or phosphines. In contrast to the trigonal bipyramide formed in donor-addition to the siliconium cation, the phosphorus cations add donors in a perpendicular fashion, depending on the nature of the pi-bonds toward phosphorus. According to quantum chemical calculations the various cations reveal different stabilities and hence a strong variation in donor addition abilities

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Publications at Bielefeld University

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oai:pub.uni-bielefeld.de:1610120Last time updated on 9/5/2013

This paper was published in Publications at Bielefeld University.

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