η3‑Furfuryl
and η3‑Thienyl Complexes of Palladium and
Platinum of Relevance
to the Functionalization of Biomass-Derived Furans

Yang Shi (175282); Peter Brenner (2055646); Stefanie Bertsch (1779532); Krzysztof Radacki (1588918); Rian D. Dewhurst (1438774)

doi:10.1021/om300568z.s001

η3‑Furfuryl and η3‑Thienyl Complexes of Palladium and Platinum of Relevance to the Functionalization of Biomass-Derived Furans

By Yang Shi (175282), Peter Brenner (2055646), Stefanie Bertsch (1779532), Krzysztof Radacki (1588918) and Rian D. Dewhurst (1438774)

Abstract

A number of cationic and neutral η3-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous η3-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition

Topics: Biophysics, Biochemistry, Biotechnology, Space Science, Environmental Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, Physical Sciences not elsewhere classified, chloromethylfurfural, Relevance, Functionalization, crystallography, ligand, Analogou, FuransA, cationic, complex, decomposition, Furfuryl, Palladium, thienyl, heteronuclear correlation NMR spectroscopy, Complexe, furfuryl, fructose, palladium, solution, Thienyl

Year: 2012

DOI identifier: 10.1021/om300568z.s001

OAI identifier: oai:figshare.com:article/2497318

Provided by: FigShare

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η<sup>3</sup>‑Furfuryl and η<sup>3</sup>‑Thienyl Complexes of Palladium and Platinum of Relevance to the Functionalization of Biomass-Derived Furans

Abstract

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