<i>C</i><sub>3</sub>‑Symmetrical Tribenzotriquinacene Derivatives: Optical Resolution through Cryptophane Synthesis and Supramolecular Self-Assembly into Nanotubes
Abstract
Based on a regioselective tris-formylation of a tribenzotriquinacene (TBTQ) hydrocarbon, the racemic <i>C</i><sub>3</sub>-symmetrical TBTQ-trialdehyde and the corresponding TBTQ-trimethanol were synthesized along with their <i>C</i><sub>1</sub>-isomers. Conversion of the <i>C</i><sub>3</sub>-trialdehyde to three diastereomeric TBTQ-based cryptophanes occurring in high yield enabled the preparation of the optically pure <i>C</i><sub>3</sub>-symmetrical TBTQ-trialdehydes and the determination of their absolute configuration. The racemic <i>C</i><sub>3</sub>-symmetrical TBTQ-trimethanol was found to form several stable nanotubular aggregates in the solid state- Dataset
- Dataset
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- Conversion
- Optical Resolution
- Derivative
- NanotubesBased
- hydrocarbon
- TBTQ
- diastereomeric
- regioselective
- cryptophane
- racemic
- nanotubular aggregates
- Tribenzotriquinacene
- Cryptophane Synthesis
- configuration
- Supramolecular
- preparation
- tribenzotriquinacene
- determination
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This paper was published in FigShare.
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