Nickel-Catalyzed Formal Homocoupling of Methoxyarenes for the Synthesis of Symmetrical Biaryls via C–O Bond Cleavage


A new method has been developed for the nickel-catalyzed homocoupling of methoxyarenes via C–O bond cleavage using a diboron reagent. The use of 1,3-dicyclohexylimidazol-2-ylidene as a ligand was found to be critical to the success of the reaction. This new method allows the synthesis of a wide range of biaryl compounds

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oai:figshare.com:article/2097730Last time updated on 2/12/2018

This paper was published in FigShare.

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