10.1021/jacs.5b12008.s002

Hydride Attack on a Coordinated Ferric Nitrosyl: Experimental and DFT Evidence for the Formation of a Heme Model–HNO Derivative

Abstract

Heme–HNO species are crucial intermediates in several biological processes. To date, no well-defined Fe heme–HNO model compounds have been reported. Hydride attack on the cationic ferric [(OEP)­Fe­(NO)­(5-MeIm)]­OTf (OEP = octaethylporphyrinato dianion) generates an Fe–HNO product that has been characterized by IR and <sup>1</sup>H NMR spectroscopy. Results of DFT calculations reveal a direct attack of the hydride on the N atom of the coordinated ferric nitrosyl

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oai:figshare.com:article/2057847Last time updated on 2/12/2018

This paper was published in FigShare.

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