High-Resolution Electron Spectroscopy of Gas-Phase Metal−Aromatic Complexes


High-resolution electron spectroscopy combines pulsed field ionization zero-electron kinetic energy (ZEKE) detection with in situ laser-assisted synthesis and supersonic expansion. The technique offers sub-meV spectral resolution for the electron spectra of metal complexes and is a powerful tool to study their bonding and structures. This Perspective presents recent progress in single-photon ZEKE spectroscopy of metal−aromatic complexes and focuses on the determination of the electron spin multiplicities, metal binding sites and modes, rotational conformers, and conformational changes of these critical species in organometallic chemistry

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oai:figshare.com:article/2057916Last time updated on 2/12/2018

This paper was published in FigShare.

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