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A mild and efficient synthesis of new pentafluorosulfanyl- substituted electron-deficient alkenes and allylsilanes

By Ewelina Falkowska, Franck Suzenet, J.-P. Bouillon, Philippe Jubault and Xavier Pannecoucke

Abstract

International audienceA series of pentafluorosulfanyl-substituted acrylic esters and amides have been synthesized in moderate to good yields from 3-pentafluorosulfanyl-prop-2-enol employing a chromic oxidation and subsequent coupling reaction. New pentafluorosulfanyl-substituted allylsilanes were also obtained from a SF5-Cl addition on allylsilanes followed by a β-elimination reaction

Topics: [CHIM.ORGA]Chemical Sciences/Organic chemistry, [CHIM.ANAL]Chemical Sciences/Analytical chemistry, [CHIM.CATA]Chemical Sciences/Catalysis, [CHIM.CHEM]Chemical Sciences/Cheminformatics, [CHIM.THER]Chemical Sciences/Medicinal Chemistry, [CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry
Publisher: 'Elsevier BV'
Year: 2014
DOI identifier: 10.1016/j.tetlet.2014.06.117
OAI identifier: oai:HAL:hal-01149559v1
Provided by: HAL-CEA
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