A mild and efficient synthesis of new pentafluorosulfanyl- substituted electron-deficient alkenes and allylsilanes


International audienceA series of pentafluorosulfanyl-substituted acrylic esters and amides have been synthesized in moderate to good yields from 3-pentafluorosulfanyl-prop-2-enol employing a chromic oxidation and subsequent coupling reaction. New pentafluorosulfanyl-substituted allylsilanes were also obtained from a SF5-Cl addition on allylsilanes followed by a β-elimination reaction

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Last time updated on December 18, 2017

This paper was published in HAL-CEA.

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