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Amino-borane oligomers bound to a Rh(i) metal fragment

By Romaeo Dallanegra, Adrian B. Chaplin, Jennifer Tsim and Andrew S. Weller


Coordination complexes of previously observed intermediates, H(3)B center dot NMe(2)BH(2)center dot NMe(2)H and [H(2)BNMeH](3), in the transition metal catalysed dehydrocoupling of H(3)B center dot NMe(2)H and H(3)B center dot NMeH(2) have been isolated and structurally characterised using the [Rh{PR(2)'(eta(2)-C(5)H(7))}](+) fragment. Their onward reactivity shows that further dehydrogenation is not a simple intramolecular process

Topics: QD
Publisher: Royal Society of Chemistry
Year: 2010
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