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An anionic weak acceptor 2-aminomethylsulfo-3,5,6-trichloro-1, 4-benzoquinone and its BEDT-TTF-based charge-transfer salts

By Hiroki Akutsu, Jun-ichi Yamada, Shin'ichi Nakatsuji and Scott S. Turner

Abstract

We have prepared a novel organic anionic weak acceptors 2-aminomethylsulfo-3,5,6-trichloro-1,4-benzoquinone (1), as a PPh4 salt. Cyclic voltammetry indicates that its reduction potential is 0.53 V lower than that of chloranil. Electrocrystallisation with BEDT-TTF cave two salts. beta-beta-(BEDT-TTF)(2)(1)-0.5H(2)O (2) and beta"-(BEDT-TTF)(2)(1).CH3OH (3). Their crystal structures and physical properties are reported

Topics: QC
Publisher: Pergamon
OAI identifier: oai:wrap.warwick.ac.uk:31249
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