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PREPARATION AND CHARACTERIZATION OF NOVEL ORGANOINDIUM DERIVATIVES - X-RAY CRYSTAL-STRUCTURE OF DIMETHYL(SALICYLALDEHYDE)INDIUM

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Abstract

The reaction of trimethylindium with one equivalent of salicylaldehyde, 2-carboxybenzaldehyde, 2-pyrrolidinone or N,N'-diphenylacetamidine results in the formation of the corresponding dimethylindium derivatives in good yields. The product obtained from the reaction with salicylaldehyde has been shown by a single crystal X-ray diffraction study to consist of centrosymmetric dimers with five-coordinate indium atoms, In-C 2.122(5), In-O(CHO) 2.341(4), In-O(OH) 2.188(3) and 2.383(3) angstrom. The reactions between triethylindium and phenylacetylene and ethanolamine are described

Topics: QD
Publisher: ELSEVIER SCIENCE SA LAUSANNE
OAI identifier: oai:wrap.warwick.ac.uk:22500
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