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CHEMICAL-SHIFT PHOTOELECTRON DIFFRACTION FROM MOLECULAR ADSORBATES

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Abstract

By using the chemical shift in core-level photoemission from adsorbed species, we apply the technique of energy-scan photoelectron diffraction to molecules containing nonequivalent atoms of the same element. As an example, we demonstrate the complete structural characterization of the surface acetate species on Cu{110} including independent determination of the sites of the two inequivalent carbon atoms

Topics: QC
Publisher: AMERICAN PHYSICAL SOC
OAI identifier: oai:wrap.warwick.ac.uk:21669
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