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(Z)-ETHYL 2-CYANO-3-METHYLSULFINYL-3-METHYLTHIOPROPENOATE

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Abstract

The title compound, C8H11NO3S2, is shown to be formed in the oxidation of ethyl 2-cyano-3,3-bis(methyl-thio)propenoate with 3-chloroperoxybenzoic acid. The compound contains an (S-2)C=C(C-2) unit which is not exactly planar, as indicated by atomic deviations of +/-0.130(1)Angstrom from the least-squares plane through these six atoms. The C-S bond lengths are unexceptional but the bond between the CH3(O)S-group and the alkene C atom is slightly longer than expected [1.837 (3) Angstrom]

Topics: QD
Publisher: MUNKSGAARD INT PUBL LTD
OAI identifier: oai:wrap.warwick.ac.uk:19419
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