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TETRAKIS(MU-ACETATO-O-O')BIS(1,5,9-TRIAZA CYCLODODECANE-2,4-DIONE-N-9)DICOPPER(II)(CU-CU)

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Abstract

The title compound, [Cu-2(C2H3O2)(4)(C9H17N3O2)(2)], is centrosymmetric and consists of a tetrakis(acetato)-bridged dinuclear copper(II) core with two unidentate N-donor axial ligands, each coordinated via the secondary amine N atom rather than through one of the two amide N atoms. The Cu-Cu distance of 2.702 (3)Angstrom is longer than previously reported for copper(II) acetate dimers of this type. Intermolecular hydrogen bonding occurs between the amide O and N atoms

Topics: QD
Publisher: MUNKSGAARD INT PUBL LTD
OAI identifier: oai:wrap.warwick.ac.uk:19231
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