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{Tris [N-(salicylidene)-2-aminoethyl]amine}tin(IV) iodide acetonitrile solvate

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Abstract

The crystal structure of the title compound, [Sn(C27H27N4O3)]I.0.5CH(3)CN, involves two almost identical complex cations in the asymmetric unit. These cations contain Sn atoms in a pseudo-octahedral environment with facial coordination of the azomethine N and the phenolate O atoms. The average Sn-O and Sn-N bond lengths are 2.048 (4) and 2.192 (5) Angstrom, respectively, while the apical N atom in the ligand is considered to be non-bonded at an average distance of 2.687 (5) Angstrom from the Sn atom

Topics: QD
Publisher: MUNKSGAARD INT PUBL LTD
OAI identifier: oai:wrap.warwick.ac.uk:16466
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