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Unexpected viability of pyridyl methanimine-based ligands for transition-metal-mediated living radical polymerization in aqueous media at ambient temperature

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Abstract

Pyridylmethanimine-based ligands are used in aqueous media at neutral pH for the efficient living radical polymerization of hydrophilic monomers. High conversions (>90%), good molecular weight control, and low polydispersities (M-w/M-n < 1.20) were obtained for the polymerization of monomethoxy-capped oligo(ethylene glycol) methacrylate at 20 <degrees>C; faster rates, reduced control, and higher polydispersities were obtained at elevated temperatures

Topics: QD
Publisher: AMER CHEMICAL SOC
OAI identifier: oai:wrap.warwick.ac.uk:12533
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