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A soluble-polymer system for the asymmetric transfer hydrogenation of ketones

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Abstract

The appropriate combination of methaerylate polymers permits the synthesis of a soluble polymer for use in ruthenium(II)-catalyzed asymmetric transfer hydrogenation reactions. Using a 7:3 copolymer of a poly(ethylene glycol) ester and a hydroxyethyl ester, a derived ruthenium(II)/ norephedrine complex catalyses reduction of acetophenone in up to 95% yield and 81% ee

Topics: QD
Publisher: AMER CHEMICAL SOC
OAI identifier: oai:wrap.warwick.ac.uk:8173
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