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EPR Study of N2H4+ Radicals in N2H5Al(SO4)2•12H2O

By [[author]]張正中, [[author]]Jenq-Jong Jang, 張正中 and Jenq-Jong Jang

Abstract

[[abstract]]本實驗是以電子順磁共振 (EPR) 的方法研究 N2H5Al(SO4)2•12H2O (可 縮寫成N2H5Al-alum)於溫度300K經γ射線照射後所產生的順磁N2H4+自由 基。 N2H5Al-alum 晶體經γ射線照射後,可測得N2H4+自由基,由EPR譜 線知道 N2H4+具有軸對稱。對稱軸方向平行原立方晶的[1 1 1]方向,其g 值,氫核 裂為軸對稱,並且氫核和氮核的超微細分裂值恰巧相等。

Topics: 電子順磁共振;自由基;超微細分裂, EPR; free radical; hyperfine splitting, [[classification]]38
Year: 2010
OAI identifier: oai:ir.lib.ntnu.edu.tw:309250000Q/8025
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