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Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato-κ5O,N,N′,O′:O}bis[chloridomanganese(III)]

By Robert D. Pike, T. Radhakrishnan and V. S. Thampidas

Abstract

The title compound, [Mn2(C18H18N2O2)2Cl2], was synthesized by the reaction between manganese(II) o-chlorobenzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The centrosymmetric dimer contains two Jahn–Teller-distorted manganese(III) ions, each in an octahedral geometry, connected through two phenoxy bridges from two ligands

Topics: Chemistry, QD1-999, Science, Q, DOAJ:Chemistry (General), DOAJ:Chemistry
Publisher: International Union of Crystallography
Year: 2008
DOI identifier: 10.1107/S1600536808000226
OAI identifier: oai:doaj.org/article:07b59be854f142cabd8428642cdf2dab
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