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(Bipyridine-κ2N,N′)chlorido[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zinc(II)

By Fatin Allia Mohamad, Ibrahim Baba, Mohamed Ibrahim Mohamed Tahir and Edward R. T. Tiekink

Abstract

The ZnII atom in the title compound, [Zn(C6H12NOS2)Cl(C10H8N2)], is coordinated by a chelating N-2-hydroxyethyl-N-isopropyldithiocarbamate ligand, a 2,2′-bipyridine ligand and a Cl atom. The resulting ClN2S2 donor set defines a distorted square-pyramidal coordination geometry. Helical supramolecular chains sustained by O—H...S hydrogen bonds and propagating along the b axis feature in the crystal packing. A three-dimensional architecture is stabilized by C—H...O, C—H...S and C—H...Cl interactions

Topics: Chemistry, QD1-999, Science, Q, DOAJ:Chemistry (General), DOAJ:Chemistry
Publisher: International Union of Crystallography
Year: 2012
DOI identifier: 10.1107/S1600536812027626
OAI identifier: oai:doaj.org/article:0152d908fd25482f80d8e96a18a7744f
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