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Removal of benzylidene acetal and benzyl ether in carbohydrate derivatives using triethylsilane and Pd/C

By Abhishek Santra, Tamashree Ghosh and Anup Kumar Misra

Abstract

Clean deprotection of carbohydrate derivatives containing benzylidene acetals and benzyl ethers was achieved under catalytic transfer hydrogenation conditions by using a combination of triethylsilane and 10% Pd/C in CH<sub>3</sub>OH at room temperature. A variety of carbohydrate diol derivatives were prepared from their benzylidene derivatives in excellent yield

Topics: benzylidene, glycoside, Pd/C, transfer hydrogenation, triethylsilane, Organic chemistry, QD241-441, Chemistry, QD1-999, Science, Q, DOAJ:Organic Chemistry, DOAJ:Chemistry
Publisher: Beilstein-Institut
Year: 2013
DOI identifier: 10.3762/bjoc.9.9
OAI identifier: oai:doaj.org/article:3b586aba2dc444fca8fdecbb5341ac26
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