Location of Repository

Polymeric strontium ranelate nonahydrate

By Kenny Stahl, Christian G. Frankaer, Anders C. Raffalt, S&amp and Jens E. T. Andersen

Abstract

The title compound, poly[[μ-aqua-tetraaqua{μ-5-[bis(carboxylatomethyl)amino]-3-carboxylatomethyl-4-cyanothiophene-2-carboxylato}distrontium(II)] tetrahydrate], [Sr2(C12H6N2O8S)(H2O)5]·3.79H2O, crystallizes with nine- and eight-coordinated Sr2+ cations. They are bound to seven of the eight ranelate O atoms and five of the water molecules. The SrO8 and SrO9 polyhedra are interconnected by edge-sharing, forming hollow layers parallel to (011). The layers are, in turn, interconnected by ranelate anions, forming a metal–organic framework (MOF) structure with channels along the a axis. The four water molecules not coordinated to strontium are located in these channels and hydrogen bonded to each other and to the ranelates. Part of the water H atoms are disordered. The compound dehydrates very easily and 0.210 (4) water molecules out of nine were lost during crystal mounting causing additional disorder in the water structure

Topics: Chemistry, QD1-999, Science, Q, DOAJ:Chemistry (General), DOAJ:Chemistry
Publisher: International Union of Crystallography
Year: 2011
DOI identifier: 10.1107/S1600536811010099
OAI identifier: oai:doaj.org/article:2b6391224099486f97e0a7a3ec723b4c
Journal:
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • https://doaj.org/toc/1600-5368 (external link)
  • http://scripts.iucr.org/cgi-bi... (external link)
  • https://doaj.org/article/2b639... (external link)
  • Suggested articles


    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.