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A comparison study on hydrogen sensing performance of Pt/MoO3 nanoplatelets coated with a thin layer of Ta2O5 or La2O3

By J. Yu, Y. Liu, F.X. Cai, M. Shafiei, G. Chen, N. Motta, W. Wlodarski, K. Kalantar-zadeh and P.T. Lai

Abstract

In this work, we investigate how hydrogen sensing performance of thermally evaporated MoO3 nanoplatelets can be further improved by RF sputtering a thin layer of tantalum oxide (Ta2O5) or lanthanum oxide (La2O3). We show that dissociated hydrogen atoms cause the thin film layer to be polarised, inducing a measurable potential difference greater than that as reported previously. We attribute these observations to the presence of numerous traps in the thin layer; their states allow a stronger trapping of charge at the Pt-thin film oxide interface as compared to the MoO3 sensors without the coating. Under exposure to H2 (10 000 ppm) the maximum change in dielectric constant of 45.6 (at 260 °C) for the Ta2O5/MoO3 nanoplatelets and 31.6 (at 220 °C) for La2O3/MoO3 nanoplatelets. Subsequently, the maximum sensitivity for the Ta2O5/MoO3 is 16.87 (at 260 °C) and La2O3/MoO3 is 7.52 (at 300 °C)

Topics: 030107 Sensor Technology (Chemical aspects), 100708 Nanomaterials, 100712 Nanoscale Characterisation, hydrogen, sensor, metal oxide, heterostructure
Publisher: IEEE
Year: 2013
OAI identifier: oai:eprints.qut.edu.au:59540
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