Article thumbnail
Location of Repository

Poly[aqua([mu]3-2-hydroxy-5-nitrobenzoato-[kappa]3O1:O1':O2)rubidium]

By Graham Smith, Urs D. Wermuth and M. L. Williams

Abstract

In the structure of title compound [Rb2(C7H4NO2)2(H2O)2]n the centrosymmetric cyclic dimeric repeating unit comprises two irregular RbO4 complex centres bridged by the carboxylate groups of the 5-nitrosalicylate ligands. The coordination about each Rb is completed by a monodentate water molecule and a phenolic O donor which gives a bridging extension [Rb-O range 3.116(7)-3.135(5)A]. The two-dimensional polymeric structure is stabilized by intermolecular water O-H...O(carboxyl) hydrogen bonds and weak inter-ring pi--pi interactions [minimum ring centroid separation, 3.620(4)A]

Topics: 030606 Structural Chemistry and Spectroscopy, crystal structure, 5-nitrosalicylic acid, rubidium, complex polymer
Publisher: Blackwell Publishing on behalf of IUCr
Year: 2011
DOI identifier: 10.1107/S1600536811037561
OAI identifier: oai:eprints.qut.edu.au:46110
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • https://eprints.qut.edu.au/461... (external link)
  • https://eprints.qut.edu.au/461... (external link)
  • Suggested articles


    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.