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2-(4-Aminophenyl)-1-phenyldiazenium 2,4,6-trinitrophenolate

By Graham Smith, Urs D. Wermuth and Jonathon M. White

Abstract

In the structure of the title salt, C12H12N3+ C6H2N3O7-, the diazenyl group of the 4-(phenyldiazenyl)aniline molecule is protonated and forms a hydrogen bond with the phenolate O acceptor of the picrate anion. Structure extension occurs through two symmetrical inter-ion three-centre amine N---H...O,O'(nitro) hydrogen-bonding associations [graph set R2/1(4)] giving a convoluted two-dimensional network structure

Topics: crystal structure, hydrogen bonding, proton transfer, picrates, aniline yellow
Publisher: Blackwell Publishing on behalf of IUCr
Year: 2011
DOI identifier: 10.1107/S1600536811008968
OAI identifier: oai:eprints.qut.edu.au:40952

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