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Raman spectroscopy of hydrotalcites with phosphate in the interlayer- implications for the removal of phosphate from water

By Ray L. Frost, Anthony W. Musumeci, J. Theo Kloprogge, Moses O. Adebajo and Wayde N. Martens

Abstract

Hydrotalcites with phosphate in the interlayer were prepared at different pH. At pH >11.0 (PO4)3- was the intercalated ionic species whereas at pH < 11.0 a mixture of (PO4)3- and (HPO4)2- ions was intercalated. Powder X-ray diffraction shows the hydrotalcite formed at pH 9.5 is poorly diffracting with a d-spacing of 11.9; whereas the d(003) spacing for the phosphate interlayered hydrotalcite formed at pH 11.9 and 12.5 were 8.0 and 7.9 Å. The addition of a thermally activated ZnAl-HT to a phosphate solution resulted in the uptake of the phosphate and the reformation of the hydrotalcite. Raman spectroscopy of the phosphate interlayered hydrotalcites shows the interlayered anion is pH dependent and only above pH 11.9 is the orthophosphate anion intercalated. At lower pH the monohydrogen phosphate anion is intercalated. Raman spectroscopy shows that upon addition of the thermally activated hydrotalcite to an aqueous phosphate solution results in the uptake of phosphate anion from the solution

Topics: hydrotalcite, brucite, phosphate removal, Raman microscopy, carrboydite, hydrohonessite, takovite, mountkeithite
Publisher: John Wiley & Sons Inc
Year: 2006
DOI identifier: 10.1002/jrs.1500
OAI identifier: oai:eprints.qut.edu.au:4760

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