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Stannylene and germylene as powerful dechlorinated reagents : new route to diphosphene

By Michael Veith, Volker Huch, Jean-Pierre Majoral, Guy Bertrand and Georges Nanuel

Abstract

Dichlorophosphines RPCl2 [R=Cl ( ), Ph ( ) and 2,4,6-But3C6H2 ( ] are reduced to the corresponding phosphorus-I compounds by the stannylene Me2Si (NBut)2Sn: ( ) or by the germylene GeI2 ( ) ; in the case of the reaction of ( ) with (bis(2,4,6-tri-tert-butylphenyl)-diphosphene ( ) is obtained with a 65 % yield

Topics: Phosphor-substituierte Verbindungen, Chemistry and allied sciences
Publisher: Sonstige Einrichtungen. INM Leibniz-Institut für Neue Materialien
Year: 1983
OAI identifier: oai:scidok.sulb.uni-saarland.de:1889

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