Physical characteristics of nanoparticles emitted during drilling of silica based polyamide 6 nanocomposites.

During the past decade, polymer nanocomposites have emerged as a novel and rapidly developing class of materials and attracted considerable investment in research and development worldwide. However, there is currently a lack of information available in the literature on the emission rates of particles from these material. In this study, real-time characterization of the size distribution and number concentration of sub-micrometer-sized particles (5.6-512 nm) emitted from polyamide 6 nanocomposites during mechanical drilling was made. For the first time, four different silica based filler of commonly use were assessed. Further, the respective emission rates were determined based on the particle population and the time. The measurements showed that the particle emission rates ranged from 1.16E+07 (min−1) to 1.03E+09 (min−1) and that the peak diameters varied from 29.6 to 75.1 nm. Airborne particles in the nanometer range (11.1-46.8 nm), in the ultrafine range (51.3-101.1 nm) and in the accumulation mode range (111.9-521 nm) accounted for 34.1% to 76.6%, 8.3% to 47% and 4.1% to 24.2% of the total emission rates, respectively, depending on the type of filler. Additionally, deposited particles were sampled and characterized, to explore any possible correlation between deposited and airborne particles. The result clearly showed that with increasing airborne particle concentration the deposit particle concentration decreased and vice verse

Tannin-based flax fibre reinforced composites for structural applications in vehicles.

Innovation is often driven by changes in government policies regulating the industries, especially true in case of the automotive. Except weight savings, the strict EU regulation of 95% recyclable material-made vehicles drives the manufactures and scientists to seek new 'green materials' for structural applications. With handing at two major drawbacks (production cost and safety), ECHOSHELL is supported by EU to develop and optimise structural solutions for superlight electric vehicles by using bio-composites made of high-performance natural fibres and resins, providing enhanced strength and bio-degradability characteristics. Flax reinforced tannin-based composite is selected as one of the candidates and were firstly investigated with different fabric lay-up angles (non-woven flax mat, UD, [0, 90°]4 and [0, +45°, 90°, −45°]2) through authors' work. Some of the obtained results, such as tensile properties and SEM micrographs were shown in this conference paper. The UD flax reinforced composite exhibits the best tensile performance, with tensile strength and modulus of 150 MPa and 9.6 MPa, respectively. It was observed that during tension the oriented-fabric composites showed some delamination process, which are expected to be eliminated through surface treatment (alkali treatment etc.) and nanotechnology, such as the use of nano-fibrils. Failure mechanism of the tested samples were identified through SEM results, indicating that the combination of fibre pull-out, fibre breakage and brittle resins failure mainly contribute to the fracture failure of composites

There are too many, but never enough: qualitative case study investigating routine coding of clinical information in depression.

Background: We sought to understand how clinical information relating to the management of depression is routinely coded in different clinical settings and the perspectives of and implications for different stakeholders with a view to understanding how these may be aligned. Materials and Methods: Qualitative investigation exploring the views of a purposefully selected range of healthcare professionals, managers, and clinical coders spanning primary and secondary care. Results: Our dataset comprised 28 semi-structured interviews, a focus group, documents relating to clinical coding standards and participant observation of clinical coding activities. We identified a range of approaches to coding clinical information including templates and order entry systems. The challenges inherent in clearly establishing a diagnosis, identifying appropriate clinical codes and possible implications of diagnoses for patients were particularly prominent in primary care. Although a range of managerial and research benefits were identified, there were no direct benefits from coded clinical data for patients or professionals. Secondary care staff emphasized the role of clinical coders in ensuring data quality, which was at odds with the policy drive to increase real-time clinical coding. Conclusions: There was overall no evidence of clear-cut direct patient care benefits to inform immediate care decisions, even in primary care where data on patients with depression were more extensively coded. A number of important secondary uses were recognized by healthcare staff, but the coding of clinical data to serve these ends was often poorly aligned with clinical practice and patient-centered considerations. The current international drive to encourage clinical coding by healthcare professionals during the clinical encounter may need to be critically examined

Weight loss and ethnicity: a cohort study of the effects induced by a very low calorie diet.

We aimed to determine whether British Asians of Indian or Pakistani descent differed in their baseline characteristics and in response to a twelve-week, very-low-calorie diet (VLCD). We then assessed whether or not a VLCD had a different effect on Asians and Caucasians, in terms of changes in weight and waist circumference. Weight loss was achieved using a nutritionally-complete VLCD with an average daily intake of 550kcal, using greater than or equal to 50g protein, greater than or equal to 50g carbohydrate, mean 15.9g fats, and greater than or equal to 100% of the recommended daily allowances (RDA) for key vitamins and minerals. The VLCD was used alongside a unique behaviour-change programme, called LighterLife (LL). Data were analysed for Asians who were recruited onto LL in 2009/2010, and for whom twelve-week weight change information was available. Waist circumference data were available for a subset of Asians, including age, body mass index and gender. These were matched to a Caucasian population and compared by independent t-test. No differences were observed between the Indian and Pakistani group for baseline measurements or weight change at twelve weeks. Caucasians had a greater percent excess body weight loss (%EBWL) than Asians at twelve weeks (72.4 ± 22.1 vs 48.9 ± 18.0, p < 0.0001). However, Asians had a greater waist circumference reduction per kilogram of weight loss when compared to Caucasians (1.16 ± 0.7 vs 0.95 ± 0.3, p = 0.037). It appears that, despite a greater %EBWL for Caucasians, Asians had a greater waist circumference reduction per kilogram of weight loss using a VLCD approach for a twelve-week period

Public engagement and participation in sustainable transport issues.

Currently, emissions from transport represent a quarter of Scotland's total. While the Scottish Government has identified a number of transport policies, which would contribute to Scotland's ability to meet its targets, action to significantly reduce greenhouse gas emissions from transport has been limited, poorly integrated with other areas of policy, and focused on narrow programmes. Drawing on best practice from cities across the North Sea Region, this paper considers how public engagement can be utilised within the development of holistic low carbon urban development. Consideration of regions where strategies have been successful reveals a context where transport is considered as part of wider urban design and urban development, thus ensuring that the potential benefits are directly related to concerns of planning, housing and behavioural change. The paper includes information and conclusions from a case study in Aberdeen, Scotland

Cross-platform access control for mobile web applications.

Web browsers are a common platform for delivering cross-platform applications. However, they currently fail to provide consistent access control for security and privacy sensitive JavaScript APIs, such as geolocation and local storage. This problem is exacerbated by new HTML5 APIs and the increasing number of personal devices people own and use. In this paper we present the webinos platform which aims to provide a single, cross-device policy system for web applications on a wide range of web-enabled devices including TVs, smartphones, in-car systems and PCs. webinos solves the existing deficiencies in web authorisation by introducing the concept of a personal zone, the set of all devices and services owned by a particular user. All devices in this zone can synchronize their access control policies through interoperable middleware and can create flexible rules which may refer to an individual user, device or the entire zone. We provide details of the architecture and explain how our experience during design highlighted several conceptual challenges

The entrepreneurial process and the role of gender: a comparative study of entrepreneurs in the business services and technology sectors in Scotland.

The comparatively low levels of entrepreneurship in Scotland and in particular, low rates of female entrepreneurship are well documented and have been the focus of numerous government policies. In addition, there are specific issues regarding female entrepreneurship and whilst current literature broadly agrees that female owned businesses lag behind male owned business in terms of size and growth of the enterprise, the reasons for these differences are highly contested with no comprehensive explanations. This thesis seeks to explore the entrepreneurial process and the lived experiences of male and female entrepreneurs in Scotland to help shed further light on the situation. Utilising a phenomenological approach and deliberately avoiding leading participants on the issue of gender, the fieldwork yielded insights into gender and entrepreneurship in the Scottish context. The heterogeneity of female entrepreneurs became apparent, leading to the emergence of a new typology regarding how these entrepreneurs perceive and manage their gender. Further key findings also include the pivotal importance of the role of sector on the entrepreneurs experiences and the influence of their previous education and work experience on their entrepreneurial experiences. Similarities also emerged between male and female entrepreneurs in their experiences and attitudes towards a number of issues in entrepreneurship. Exploring the research findings through the theoretical lenses provided by Liberal Feminism, Social Feminism and the Theory of Effectuation helped to derive useful insight that contributes towards the calls for a new female entrepreneurship theory

Very-low-energy diets and morbidity: a systematic review of longer-term evidence.

Evidence from the literature supports the safe use of very-low-energy diets (VLED) for up to 3 months in supervised conditions for patients who fail to meet a target weight loss using a standard low-fat, reduced-energy approach. There is, however, a need for longer-term outcomes on obesity and associated morbidities following a VLED. The present systematic review aims to investigate longer-term outcomes from studies using VLED, with a minimum duration of 12 months, published between January 2000 and December 2010. Studies conducted in both children and adults, with a mean/median BMI of ≥ 28 kg/m2 were included. PubMed, MEDLINE, Web of Science and Science Direct were searched. Reference lists of studies and reviews were manually searched. Weight loss or prevention of weight gain and morbidities were the main outcomes assessed. A total of thirty-two out of 894 articles met the inclusion criteria. The duration of the studies ranged from 12 months to 5 years. Periods of VLED ranged from 25 d to 9 months. Several studies incorporated aspects of behaviour therapy, exercise, low-fat diets, low-carbohydrate diets or medication. Current evidence demonstrates significant weight loss and improvements in blood pressure, waist circumference and lipid profile in the longer term following a VLED. Interpretation of the results, however, was restricted and conclusions with which to guide best practice are limited due to heterogeneity between the studies. The present review clearly identifies the need for more evidence and standardised studies to assess the longer-term benefits from weight loss achieved using VLED

Whole life costing optimisation with integrated logistics support considerations.

It has long been recognised that, in the military sector, the Integrated Logistics Support ILS can significantly enhance system effectiveness and add value to their competitiveness. Hence, it is not surprising that many organisations outside to the military support the ILS adoption to increase their competence level. Even though the ILS underlying theory is general, there is a lack of suitable methodology that facilitates ILS implementation in other industries such as Oil & Gas industry. In particular when considering complex systems with long life-span, the optimisation of maintenance-related activities is important to fulfil system readiness, safety and whole life cost requirements. Modern petroleum equipment like gas turbines and drilling rigs are dependent on readily available maintenance supports in order to maximise their operational ability. Therefore, it has been identified that the study should be conducted to an effective use of ILS with the petroleum industry. In doing so, the usage of the ILS framework as a decision tool for maintenance optimisation is outlined. This framework embraces ILS concepts to support asset managers in developing their maintenance strategies. Level of repair analysis and spare parts management have been identified as potential areas for enhancing the use of ILS. In particular, maintenance optimisation is approached as a trade-off between investment in spare parts level and repair capacity. The developed framework delivers cost-effective support strategies obtained with iterative optimisation algorithm built on heuristics and genetic algorithm techniques. Finally, this algorithm has been implemented into computational algorithms. The framework can be employed to identify the optimum level of spare parts and the optimum amount of repair capacity for multi echelon repair network and multi-indenture systems. The framework has been used to carry out optimisations intended to maximise the availability of gas turbines by varying logistics support parameters. Typical results have shown that a joint optimisation of spare parts and level of repair analysis leads to better results than optimising them separately and emphasises the need for the developed framework. As part of this research, an expert panel validation method has been used to both refine the design of the developed framework and also evaluate its functionality from experienced practitioners within the Algerian petroleum industry. The results of this validation have demonstrated the advantages of integrating spare part management and level of repair analysis LORA to the problem of maintenance optimisation and shown that the framework is able to deliver optimal maintenance supportability decisions. The generic framework developed in this thesis can be seen a novel and comprehensive model for integrating two ILS elements into the operating tool in a manner that improves maintenance support provision, while remaining both flexible and usable; and therefore as a contribution to a better adoption of ILS technique within Algerian Petroleum Industry

Testing of a method for insulation of masonry and lath walls in existing domestic Scottish construction.

The main aim of this research project was to develop and test the feasibility of a method of insulating an existing historic listed building whilst maintaining its original architectural features. The success of the project is conditioned by the avoidance of any damage of the inner lath plaster wall leaf. The application of the feasibility study involved a trial off site to make sure the process won't bring any harm to the building. Despite these precautions, alterations of the method took place during the trial due to onsite discoveries related to the building's age and condition