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This is an update request for the document Multivariate statistical analysis of mass spectra as a tool for the classification of the main humic substances according to their structural and conformational features by R. Baigorri, Ángel M. Zamarreño, M. Fuentes Rodríguez, G. González Gaitano, José María García Mina, Gonzalo Almendros Martín and Francisco Javier González-Vila

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